1.

How the prediction of reaction is carried out ? (a) By the value of K (b) By the value of Q (c) By the value of DeltaG(d) By the value DeltaG^ө .

Answer»

SOLUTION :(a) Value of K: By the value of K information about equilibrium can be obtained.
(1) If `K_c gt 10^3`,So product is more and reaction is toward completion.
(ii) If `K_c lt 10^(-3)` , So product is negligible reaction almost not take place.
(iii) If `K_c = 10^3`to `10^(-3)` at equilibrium product and REACTANTS are comparable.
(b) Reaction predicting and Value of `Q_c`:
(1) If `Q_c ltK_c`, reaction move in forward direction.
(ii) If `Q_c gt K_c`,reaction move in reverse direction.
(iii) If `Q_c = K_c`,reaction is in equilibrium and will not move forward.
(c) Reaction of spontaneity (Predicting) and Value of `DeltaG`:
(i)`DeltaG lt 0` reaction is SPONTANEOUS.
(ii) `DeltaG gt 0`reaction is non-spontaneous.
(iii) `DeltaG = 0` reaction is in equilibrium.
(d)`DeltaG^(ө)` and K and Reaction of spontaneity :
(i) `DeltaG^(ө)lt0` means negative, So `K_cgt 1`. Reaction is spontaneity and product will be more reaction proceed in forward direction .
(ii) `DeltaG^(ө) gt 0`means positive, So `K_clt 1`. Reaction is not spontaneous and product will be less. Reaction proceed in reverse direction.
(iii) AGO = 0, K= 1 So, equilibrium state is attain.


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