1.

Hydrogenation is done of hydrogen A of unsaturated hydrocarbon on addition of H_(2). Ozonolysis of A gives acetone, acetaldehyde and propane-1, 3-diol. Give the structure and name of X ?

Answer»

Solution :(i) On hydrogenation of A, 2 moler of `H_(2)` is added. Therefore in A, there are `2pi`-bond therefore in A there is 1 double bond and 1 triple bond.
(ii) OZONOLYSIS of A gives three product.
`underset("Acetone")overset((a))(CH_(3)COCH_(3))+underset("Acetaldehyde")overset((b))(CH_(3)CHO)+ overset((c))(CHOCH_(2)CHO)`
No. of carbon `"3+2+3=8"`
(III) From above PRODUCTS, A is diene and (a), (b) and (c) has double bonds reacts with X, STRUCTURE is as follows 2-methyl hepta-2, 5-diene.
Formed product :
`(H_(3)C-overset(CH_(3))overset(|)(C))/((a))=(CH-CH_(2)-CH)/((c))=(CH-CH_(3))/((b))`
Hydrocarbon (A)


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