1.

I_(2(aq)) + I_((aq))^(-) hArr I_(3(aq))^(-).We started with I mole of I_(2)and 0.5 mole of l^(-) in one litre flask. After equilibrium is reached, excess of AgNO_(2) gave 0.25 mole of yellow precipitate. Equilibrium constant is

Answer»

1.33
2.66
2
3

Solution :`underset(1-alpha)underset(1)(I_(2(aq)))+ underset(0.5-alpha)underset(0.5)(I_((aq))^(-)) HARR underset(alpha)underset(0)(I_(3(aq))^(-))`
At equilibrium
`(0.5-alpha)` mole of `I^(-)`
reacts with `AgNO_(3)` to GAVE 0.25 mole of AGI
`:. 0.5 - alpha=0.25, alpha=0.25`
`K_(c)=([I_(3)^(-)])/([I_(2)](I^(-)))=(2)/((1-alpha)(0.5-alpha))=(0.25)/(0.75 XX 0.25)=(4)/(3)=1.33`


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