1.

(i) Explain the preparation of hydrogen using electrolysis. (ii) Why hydrogen gas is used as fuel?

Answer»

Solution :(i) High purity of HYDROGEN `(gt99.9%)` is obtained by the electrolysis of water containing traces of acid or alkali or electrolysis of aqueous solution of SODIUM hydroxide or potassium hydroxide using a NICKEL anode and iron cathode. This process is not economical for large scale production.
At anode`: 2OH^(-)toH_(2)O+1//2O_(2)+2e^(-)`
At cahotde: `2H_(2)O+2e^(-)to2OH+H_(2)`
Overall reaction: `H_(2)OtoH_(2)+1//2O_(2)`.
(ii) Hydrogen BURNS in air, virtually free from pollution and produces significant amount of energy. this reaction is used in fuel cells to generate electricity.
`2H_(2_((g)))+O_(2_((g)))to2H_(2)O_((l))+`energy.


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