1.

(I) (Na_(2)S+I_(3)^(-))+ Na_(2)SO_(3) underset("Boil")rarr Compound [A] +2NaI (II){:(A(aq)+AgNO_(3)rarr,"White ppt"[B]("unstable")),(,""darr"Turning dark on standing"),(,"Black compound"[C]):} (III) {:(A(aq)+FeCI_(3)rarr,"Dark-violet colouration"[E]),(,""darr),(,[F]"colour disappears on standing"):} The correct statement about the above observations is/are:

Answer»

Aqueous solution of 'A' on treatment with `AgNO_(3)` gives 'B' white ppt. of `Ag_(2)S_(2)O_(3)`
Aqueous solution of 'A' on treatment with `AgNO_(3)` gives white ppt. of `Ag_(2)SO_(3)`.
Compound 'C' is `Ag_(2)S`, which is black in COLOUR
The violet colouration of compound (E) is `[FE(S_(2)O_(3))_(2)]^(-)`, which turns into `FeS_(4)O_(6)`.

ANSWER :A::C::D


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