1.

(i) Why catalyst does not influence the value of equilibrium constant?(ii) What are the important differences between reversible and irreversible processes?

Answer»

The equilibrium constant NEVER depends on the type of catalyst used, no matter the nature of the reaction (homogeneous or heterogeneous). The equilibrium constant is a thermodynamic variable that is linked to the free Gibbs energy, and also varies with the temperature according to the Van't Hoff Equation. Catalysts only speed up the reaction rates; they don't have any effect on the equilibrium of the reactions.

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