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Identify correct order of reactivity in electronphilic substitution reactions of the following compounds A. `1 gt 2 gt 3 gt 4 `B. `4 gt 3 gt 2 gt 1`C. `2 gt 3 gt 1 gt 4`D. `2 gt 1 gt 3 gt 4` |
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Answer» Correct Answer - C Due to +I effect of `CH_(3)` group, toluence (2) has higher electron density than benzene (1). Out of Cl and `NO_(2), NO_(2)` group has a strong `-I` effect and -M effect while chlorine has a weak -I effect, therefore, nitrobenzene(4) has a much a lower electron density than chlorobenzene. Thus the overall reactivity order is `2 gt 3 gt 4` i.e. option C is the answer. |
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