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If B–Cl bond has a dipole moment,explain why BCl_(3) molecule has zero dipole moment. |
Answer» Solution :The ELECTRONEGATIVITY of boron is 2.0, while that of CI is 3.0. Due to the difference in electronegativity, B - CI bond is polar and has a definite dipole moment. `BCl_3` is a trigonal planar molecule due to `sp^2` hybridisation state of B in it. In `BCl_3`, the three B - Cl BONDS lie in the same plane at an angle of `120^@`. THEREFORE, the RESULTANT dipole moment of two B - Cl bonds is EQUAL in magnitude and opposite in direction to the dipole moment of the third B-Cl bond. As a result, the net dipole moment of `BCl_3` molecule is zero as shown below.
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