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If `Delta H_("ionisation")^(@)` for HCN and `CH_(3)COOH` are `45.2` and `2.1 KJ mol^(-1)` , which one of the following is correct ?A. `pK_(a(HCN))ltpK_(a(CH_(3)COOH))`B. `pK_(a(HCN))gtpK_(a(CH_(3)COOH))`C. `pK_(a(HCN))=pK_(a(CH_(3)COOH))`D. None of these |
Answer» Correct Answer - B More is heat of ionisation, more is stability of molecule or lesser is dissociation. Thus `K_(a)(CH_(3)COOH)gtK_(a)(HCN)` Therefore `pK_(a)(HCN)gtpK_(a)(CH_(3)COOH)` |
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