1.

If K_(a_(1)),K_(a_(2)) are the first, second and third ionization constants of H_(2)PO_(4) respectively and K_(a_(1)) gtgt K_(a_(2)) gtgt K_(a_(3)). Which is/are correct:

Answer»

`[H^(+)] = sqrt(k_(a_(1))[H_(3)PO_(4)])`
`[H^(+)] = [HPO_(4)^(2-)]`
`K_(a_(2)) = [HPO_(4)^(2-)]`
`K_(a_(1)) = [HPO_(4)^(2-)]`

SOLUTION :In CASE of polyprotic acids, divalent ANION concentration is equal to `K_(a_(2))`


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