If more than one phase is present in the reversible reaction then it is said to be heterogenous system. Example: CaO(s)+CO_(2)(g) Expression of equilibrium constant for the above reaction can be taken as : K=([CaO(s)][CO_(2)(g)])/([CaO(s)])."".....(i) Now concentration of CaO(s)=[CaO(s)] =("moles of CaO")/("volume of CaO") as density of CaO[rho_(CaO(s))] and molar mass of CaO[M_(CaO(s))]are a fixed quantity therefore concentration of pure solid and liquid term is uncharge with respect to time. Hence, equilibrium constant for the equation (i) can be written as : K_(C)=[CO_(2)(g))] K_(P)=P_(CO_2) As K_(p) and K_(c) is not containing solid terms therefore, addition or removel of pure solid and pure liquid has no effect on the equilibrium process. K_(p) for the reaction NH_(4)I(s)hArrNH_(3)(g)+HI(g)is 1//4 at 300K.If above equilibrium is established by taking 4 moles of NH_(4)I(s) in 100 litre contanier, then moles of NH_(4)I(s) left in the container at equilibrium is ["Taken R=1/12Lt.atm mol"^(-1)K^(-1)].