1.

If NaClis doped with 10^(-4) mol% "of" SrCl_(2)the concentration of cation vacancies will be (N_(A)=6.02times10^(23)mol^(-1))

Answer»

`6.02times10^(23) mol^(-1)`
`6.02times10^(15) mol^(-1)`
`6.02times10^(16) mol^(-1)`
`6.02times10^(17) mol^(-1)`

Solution :For each `Sr^(2+)`ion introduced, one vacancy is createdbecause `2Na^(+)`ions are REMOVED and one of the twovacant sites is OCCUPIED by `Sr^(2+)`. Doping with `10^(-4)` mol % `SrCl_(2)` means 100 moles of NaCl are doped with `10^(-4)` mole of `SrCl_(2)`.
`therefore SrCl_(2)" droped per mole of " NaCl = 10^(-4)//100`
=`10^(-6) "mole" = 10^(-6)times(6.02times10^(23))Sr^(2+) Sr^(2+)ions`
`therefore"concentration of cation VACANCIES"=6.02times10^(17) mol^(-1)`


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