1.

If pH of a saturated solution of Ba(OH)_2 is 12, the value of its K_((Sp)) is :

Answer»

`4.0xx10^(-6) M^3`
`4.0xx10^(-7)M^3`
`5.0xx10^(-6) M^3`
`5.0xx10^(-7) M^3`

Solution :`BA(OH)_(2(s)) to Ba_((aq))^(+2) + 2OH_((aq))^(-)`
pH=12 or pOH=2
`[OH^-]=10^(-2)` M
`{:(Ba(OH)_2 to , Ba^(+2)+, 2OH^-),(,0.5xx10^(-2), 10^(-2)):}`
[`because` CONCENTRATION of `Ba^(2+)` is half of `OH^-` ]
`K_(sp)= [Ba^(+2)][OH^-]^2`
`=[0.5xx10^(-2)][1.0xx10^(-2)]^2`
`=0.5xx10^(-6)=5.0xx10^(-7) M^3`


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