1.

If the equilibrium for reaction of `HCN` with `NaOH` is `10^(10)` then calculate `pH` of `10^(-3)MNaCN` solution of `25^(@)C`

Answer» `{:(,HCN+NaOH,hArr,H_(2)O,+,NaCN,K=10^(10)),(rArr,CN^(-)+ H_(2)O,hArr,HCN,+,OH^(-),K=10^(10)),(t=0,10^(-3)M,,0,,0,),(at eq.,10^(-3)(1-h),,10^(-3)h,,10^(-3)h,):}`
`K_(h)=10^(-10)=(10^(-3)hxx10^(-3)h)/(10^(-3)(1-h))rArrsqrt(K_(h)/(c ))=sqrt(10^(-7))( lt0.1)`
`pH=7-(1)/(2)log10^(-10)+(1)/(2)log10^(-10)=7+5-(3)/(2)=10.5`


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