1.

If the half-life period of a first order reaction in A is 2 minutes, how long will it take [A] to reach `25%` of its initial concentration ?

Answer» `t1//2=2min." "rArr" "t1//2=(0.693)/(K)" "rArr" "K=(0.693)/(2)=0.3465"min"^(-1)`
For `1^(st)` order reaction :
`K=(2.303)/(t)log.(a)/(a-x)" "ararr"initail concentration"`
`xrarr"reacted"`
`a-xrarr"remaining"`
`t=(2.303)/(0.3465)log.(cancel100^(4))/(cancel25_(1))" "rArr" "t=6.646xx2log2=6.46xx2xx0.3010`
`t = 4.00"mins".`


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