1.

If the positions of Na^+ and Cl^- are interchanged in NaCl , having fcc arrangement of Cl^- ions then in the unit cell of NaCl

Answer»

`NA^+` ions will decrease by 1 while `Cl^-` ions will INCREASE by 1
`Na^+` ions will increase by 1 while `Cl^-` ions will decrease by 1
Number of `Na^+` and `Cl^-` ions will REMAIN the same
The crystal STRUCTURE of NaCl wil change

Solution :In NaCl with fcc arrangement of `Cl^-` ions , number of `Cl^-` ion =14 , `Na^+` ions =13. On interchanging their positions, `Cl^-` ions will be 13 and `Na^+` ions will be 14


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