1.

If the salt M_(2)X, QY_(2) and PZ_(3) have the same solubilities, their K_(sp) values are related as

Answer»

`K_(sp) (M_(2)X) = K_(sp) (Q Y_(2)) lt K_(sp) (PZ_(3))`
`K_(sp) (M_(2)X) gt K_(sp) (Q Y_(2)) = K_(sp) (PZ_(3))`
`K_(sp) (M_(2)X) lt K_(sp) (Q Y_(2)) =K_(sp) (PZ_(3))`
`K_(sp) (M_(2)X) gtK_(sp) (Q Y_(2)) gtK_(sp) (PZ_(3))`

Solution :`M_(2)X and QY_(2)` are SALTS of the TYPE `A_(2)B` for which `K_(sp) = 4 S^(3)`. If S is same, `K_(sp)` will be equal.
For `PZ_(3) , K_(sp) = S(3S)^(3)=27S^(4), ` i.e., much higher.
Hence, (a) is the correct OPTION.


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