1.

If volume occupied by CO_2 molecules is negligible, then the pressure exerted by one mole of CO_2 gas in terms of temperature (T), assuming V to be single valued, is

Answer»

`P = (RT)/(4a)`
`P = (RT)/(4(a - B))` 
`P = (R^2 T^2)/(4a)`
`(R^2 T^2)/(4AB)`

Solution :Volume regligible `implies b = 0`
`implies (P + (an^2)/(V^2)) V = NRT`
`PV^2 + an^2 - nRT V = 0`
single value `implies ` determinant = 0
`(RT)^2 - 4Pa = 0 implies P = (R^2 T^2)/(4a)`.


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