1.

IMNH_4 OHand JMHCl are mixedto make total volume of 300 mL. If pH of the mixture is 9.26andpK_a (NH_4 ^(+)) = 9.26then volume ratio of NH_4 and HClwill be :

Answer»

`1:1`
` 1: 2`
` 2: 1`
`3:1`

SOLUTION :If VOLUME of `NH_4OH ` = xml
then HCl = ` ( 300 -x )ml`
pH of mixture= ` pKa of NH_4^(+) `
`rArr " buffer with "[S] =[B]`
`1 xx ( 300 - x)= (1 xx x )- ( 300 -x ) `
` rArr x = ( 600)/( 3 ) = 200 rArr " ratio " =(200)/(100)= (2)/(1) `


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