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In a conductivity cell the two platinum electrodes each of area 10 sq. cm are fixed 1.5 cm apart. The cell. Contained `0.05N` solution of a salt. If the two electrodes are just half dipped into the solution which has a resistance of 50 ohms, find equivalent conductance of the salt solution. |
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Answer» Correct Answer - `120 mho cm^(2) eq^(-1)` Since the electrodes of the cell are just half depped the effective area will be 5 eq cm. Cell constant `= (1)/(a) =(1.5)/(5) = 0.3 cm^(-1)` Specific conductance = conductance `x` cell constant `= (1)/("resistance") xx` cell constant `=(1)/(50)xx0.3 =(3)/(500)"mho cm"^(-1)` Equivalent conductance = specific conductance `x` volume....(8) `(3)/(500)xx 20000 = 120 "mho cm"^(2)` `(0.05 N =N//20 :. V =20,000 "cc")`. |
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