1.

In alkaline medium, H_(2)O_(2) reacts with Fe^(3+) and Mn^(2+) respectively to give

Answer»

`Fe^(4+) , and Mn^(4+)`
`Fe^(2+) and Mn^(2+)`
`Fe^(2+) and Mn^(4+)`
`Fe^(4+) and Mn^(2+)`

SOLUTION :The maximum O.S. of Fe is +3 , THEREFORE, `Fe^(3+)` can only be reduced by `H_(2)O_(2)`. In contrast , the minimum stable O.S. of Mn is +2 , therefore can be further oxidised by `H_(2)O_(2)` to + 4 oxidation state. In other words, in alkaline medium, `H_(2)O_(2)` . reduces `Fe^(3+)` to `Fe^(2+)` but is oxidises `Mn^(2+)` to `Mn^(4+)` THUS, OPTION (c) is correct.


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