1.

In an ionic compound A^+ X^- , the radii of A^+ and X^- ions are 1.0 pm and 2.0 pm respectively. The volume of the unit cell of the crystal AX will be

Answer»

`"27 pm"^3`
`"64 pm"^3`
`"125 pm"^3`
`"216 pm"^3`

Solution :`r_(A^+)/r_(X^-)=1/2`=0.5 . As it LIES in the RANGE 0.414-0.732, AX has octahedral structure like that of NaCl.
Hence, edge length (a)=`2(r_+ +r_(-))`
=2(1+2)pm =6 pm
Volume of the UNIT cell=`a^3`=`"(6 pm)"^3="216 pm"^3`


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