InterviewSolution
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InterviewSolution
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In basicity of aniline is weaker in comparison to that of methylamine due toA. hyperconjugative effect of Me group of `MeNH_(2)`B. resonance effect of phenyl group in anilineC. lower molecular mass of methylamine as compared to that of anilineD. resonance effect of `-NH_(2)` group in `MeNH_(2)` |
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Answer» Correct Answer - B The lone pair of electrons of nitrogen atom in aniline takes part in resonance and thus is not available for donation to protons. Thus aniline is less basic than `CH_(3)NH_(2)` in which `CH_(3)` group exhibits +I effect |
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