1.

In each of the following pairs of compounds, Identify the one with more covalent nature and why ? LiBe and LiI

Answer»

Solution :According to Fajan's rule,
LI I in more covalent than LiBr.
Since `I^(-)` is larger in size than `Br^(-)`, the larger sized anion PULLS the CATION EFFECTIVELY towards the nucleus.
This results in more polarisation effect .
GREATER the polarisation effect greater will be the covalent character .


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