1.

In each of the following questions, a statementof Assertion is given followed by a corresponding statementof Reason just below it. Of the statements, mark the correctanswer as Assertion . If standard free energy change of a reaction is zero , this implies that equilibrium constant of the reaction is unity . Reason . For a reaction in equilibrium , equilibrium constant is always unity .

Answer»

If both assertion and reason are true, and reason is the true explanation of the assertion .
If both assertion and reason are true but reason is the true explanation of the assertion .
If assertion is true, but reason is false.
If both assertion and reason are false .

SOLUTION :`DELTAG^(@) = -2 *303 RT LOG K `
When ` DeltaG^(@) =0, log K=0 :. K=1`
Hence, Assertion is correct .
Correct R. For a reaction in EQUILIBRIUM , the value of equilibrum constant depends upon the relative amounts of the reactants and products .


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