1.

In NaCl is doped with10^(-4) mol % ofScCl_(2) , the concentration of cation vacancies will be(N_(A) = 6.02 xx 10^(23) mol^(-1))

Answer»

` 6.02 xx 10^(14) mol^(-1)`
`6.02 xx 10^(15) mol^(-1)`
` 6.02 xx 10^(16) mol^(-1)`
` 6.02 xx 10^(17)mol^(-1) `

Solution :For each ` Sr^(2+)`ion INTRODUCED, one catio vacancy is created because` 2 Na^(+)`ions are REMOVED and one vacant site is occupied by ` Sr^(2+)` . Doping with ` 10^(-4) "mol"%" of " SrCl_(2)`means 100 moles of NaCl are doped with ` 10^(-4)` mole of ` SrCl_(2)`
`SrCl_(2)` doped per mole of NaCl = `10^(-4) //100`
` 10^(-6)` mole
=`10^(-6) xx ( 6.02 xx 10^(23)) Sr^(2+)` ions
` = 6.02 xx 10^(17) Sr^(2+)` ions
Hence, concetration of cation vacancies
` 6.02 xx 10^(17) "mol"^(-1)`


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