1.

In presence of HCl, H_(2)S results theprecipitationof group-2 radicals but not group-4 radicals during qualitative analysis. It is due to

Answer»

higher concentration of `H^(+)`
lower concentration of `H^(+)`
higher concentration of `S^(2-)`
lower concentration of `S^(2-)`

Solution :Dissociation of `H_(2)S` is suppressed in presence of HCl due to common ION EFFECT. This decreases the `S^(2-)` ion concentration and hence only GROUP 2 radicals are precipitated as they have LOW solubility products.


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