1.

In qualtiative analysis when H_(2)S is passed through aqueous solution of salt acidified with dil. HCl, a black precipitate with dill. HNO_(3), it forms a solution of blue colour. Addition of excess of aqueus soltion of ammonia to this solution gives........ .

Answer»

DEEP blue PRECIPITATE of `Cu(OH)_(2)`
deepblue solution of `[Cu(NH_(3))_(4)]^(2+)`
deep blue solution of `Cu(NO_(3))_(2)`
deep blue solution of `Cu(OH)_(2).Cu(NO_(3))_(2)`

Solution :`underset(CuSO_(4)+H_(2)Soverset(Dil.HCl)tounderset("Blck PPT.")(CuS+H_(2)SO_(4)),Cus+2HNO_(3)tounderset("Blue solution")(Cu(NO_(3))_(2))+H_(2)S`
`Cu(N_(3))_(2)+4NH_(3)tounderset(("Deep blue solution"))[[Cu(NH_(3))_(4)]^(2+)+2NO_(3)^(-)`


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