1.

In sample of hydrogen atomsin ground state, electron make transition from ground state to particular excited state, where path length isfour times of debroglie wavelenght . Electrons make back transitiontothe ground state prouducing all possible photons.

Answer»

WAVELENGHTOF photon used for this transition is 121.5 NM
Final excitd state of `Li^(+2)`is 6
kinetic energy of electronin intaial excited state of `Li^(+2)`is 13.6 eV
All are correct

Solution :`3^(rd)` highest energetic photons`rArr(13.6-3.4)eV=10.2 eV`, transition is `2 to 1`
`lambda=(hc)/(E)=(1240)/(10.2)nm=121.5nm`
For H atoms =gor `Li^(+)`ION
`13.6xx1[1-(1)/(2^(2))]=13.6xx9[(1)/(3^(2))-(1)/(6^(2))]`
`therefore`for `Li^(+)`ion transition is `3 to 6`
Initial excited state=3
Final excited state =6
K.E. ofelectronin intial excited state of `Li^(+2)`=`13.6xx(3^(3))/(3^(3))`=`13.6 eV`.


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