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In some of the reactions thallium resembles aluminium, whereas in others it resembles with group I metals. Support this statement by giving some evidences. |
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Answer» Solution :Similar to aluminium, thallium shows +3 oxidation STATE in compounds like `Tl_2 O_3, TlCl_3, Tl_2 (SO_4)_3`, ETC. It FORMS complex `[TIF_6]^(3-)` similar to that formed by aluminium,`[AlF_6]^(2-)` Due to inert-pair effect, it also exhibits oxidation state of +1 as exhibited by ALKALI metals of group 1. Some of its compounds formed in this state are `Tl_2 O , TlCl` etc., which are similar to the compounds like `Na_2 O, NACL` etc. Like `Na_2 O, Tl_2 O` is strongly basic. Thus, it resembles group 1 metals also. |
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