1.

In the electrolysis of aqueous solutoin of copper suphate using copper stirps as anode and cathode the anode rection is

Answer»

`Cu^(2+)+2e^(-)rarrCu`
`CurarrCu^(2+)+2e^(-)`
`2HO^(-)rarrH_(2)+1//2O_(2)+2e^(-)`
`2HSO_(4)^(-)rarrH_(2)S_(2)O_(8)+2e^(-)`

Solution :At ANODE oxidation occur the possible reactionwhich may occur at anode are
`Cu(s)rarrCu^(2)+2E^(-)+2E^(-),E^(@)=-0.80 v`
`2H_(2)O(l)rarrO_(2)(g)+4H^(+)(AQ)+4E^(-),E^(2)=-1.23` V
since oxidation potential of Cu ishigher than that of`H_(2)O` melecules thus OPTION (b) is correct


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