1.

In the following dehydration of diol with `H_(3)PO_(4)` following product is formed such that isotopic `.^(18)O` goes `H_(2)O`. Explain.

Answer» Correct Answer - `3^(@)` alcohol at `C_(2)` is more basic than `2^(@)` alcohol at `C_(5)`. Henc,e intramolecular dehydration takes place such that H of `2^(@)` alcoholic group at `C_(5)` eliminated `OH` of `3^(@)` alcoholic groupa at `C_(2)`(with isotopic `.^(18)O`)


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