1.

In the following reaction: 4NO_(2)(g) + O_(2)(g) to 2N_(2)O_(5)(g),DeltaH = - 110 kJ, if N_(2)o_(5)(s) is formed instead of N_(2)O_(5)(g) in the reaction, the enthalpy change (in kJ) would be (enthalpy of sublimation of N_(2)O_(5)(s) is + 53 kJ mol^(-1)).

Answer»

`-216`
`-162`
`+108`
`+216`

Solution :(i) `4NO_(2)(g) + O_(2)(g) to 2N_(2)O_(5)(g), DeltaH = -110kJ`
GIVEN that
(ii) `N_(2)O_(5)(s) to N_(2)O_(5)(g) , DeltaH = 53 kJ"mol"^(-1)`
(iii)`2N_(2)O_(5)(s) to 2N_(2)O_(5)(g), DeltaH = 106 kJ"mol"^(-1)`
Subtracting eq.(iii) from (i),
`4NO_(2)(g) +O_(2)(g) to 2N_(2)O_(5)(s)`
then `DeltaH = -110-106 = -216 kJ"mol"^(-1)`


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