In the lollowing reuction. AgCl +KIhArr KCl + Agl. As Kl is added, the cquilibrium is shifted towards right giving more Agl precipitate, because

In the lollowing reuction. AgCl +KIhArr KCl + Agl. As Kl is added, the

1.	In the lollowing reuction. AgCl +KIhArr KCl + Agl. As Kl is added, the cquilibrium is shifted towards right giving more Agl precipitate, because
Answer» Both AgCl and Agl are sparingly soluble The `K_(SP) ` of Agl is lower than `K_(sp) ` of AgCl The `K_(sp) `of AG I is higher than `K_(sp) ` of AgCl Both AgCl and Agl have same solubility PRODUCT. Solution :`AgCl_((s)) HARR Ag^(+) +Cl^(-) , Ksp_1` `AgI_((s)) hArr Ag^(+) +I^(-) ,KsP_2` ` AgCl+I^(-) hArr AgI +Cl^(-),K =(Ksp_1)/(Ksp_2) ` as ` I^(-) `is ADDED equation shifts to the right ` rArr K gt 1 rArr (Ksp_1)/(Ksp_2) gt 1 `