1.

In the reaction of sodium thiosulphate with I_(2)in aqueous medium the equivalent weight of sodium thiosulphate is equal to

Answer»

Molar MASS of sodium thiosulphate
The average of molar masses of `Na_(2)S_(2)O_(3)` and `I_(2)`
Half the molar mass of sodium thiosulphate
Molar mass of SODIU thiosulphate `xx 2`

Solution :`2Na_(2)S_(2)O_(3)*5H_(2)O + I_(2) rarr 2NaI + Na_(2) S_(4) O_(6)` or
`:.2S_(2)O_(3)^(3-) rarr S_(4)O_(6)^(2-) +2e^(-)`
Equivalent weight of `Na_(2)S_(2)O_(3) . 5H_(2)O`
`= ("Mol. Wt.")/(1) = (248)/(1) = 248`


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