1.

In the standardization of Na_(2)aS_(2)O using K_(2)Cr_(2)O_(7) by iodmetry the equivalent weight of K_(2)Cr_(2)O_(7) is

Answer»

`("MOLECULAR weight")//2`
`("molecular weight")//6`
`("molecular weight")//3`
same as molecular weight

Solution :`Cr_(2)O_(7)^(2-)+14H^(+)+6e^(-)rarr2Cr^(3+)+7H_(2)O`
Since `K_(2)Cr_(2)O_(7)` accepts 6 electrons for its REDUCTION to `Cr^(3+)` ions
`therefore` Eq. wt. `=` MOL wt/ 6


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