1.

In which of the following pairs, the two species are lso-structure ?

Answer»

`SO_(3)^(2-) and NO_(3)^(-)`<BR>`BF_(3) and NF_(3)`
`BrO_(3)^(-) and XeO_(3)`
`SF_(4) and XeF_(4)`

Solution :`BrO_(3)^(-) and XeO_(3)`
HYBRIDIZATION of Br is `BrO_(3)^(-)`
Total valence electrons = 7 + 3 `xx 6 ` = 25
Charge = -1 hence
Total 25 +1 = 26
`= (26)/(8) = 3 ` (Q) + 2 (R) = 5
Hybridization= `dsp^(3)`
Hybridization of Xe in` XeO_(3)`
Total valence electrons = 8 + 3 `xx 6` = 26
= ` (26)/(8) = 3 (Q) + 2 (R) = 5 `
Hybridization = `dsp^(3)`
In both cases , the structure is TRIGONAL pyramidal.


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