1.

In which of the following structures coordination number for cations and anions in the packed structure will be same? (i) Cl– ion form fcc lattice and Na+ ions occupy all octahedral voids of the unit cell. (ii) Ca2+ ions form fcc lattice and F – ions occupy all the eight tetrahedral voids of the unit cell. (iii) O2– ions form fcc lattice and Na+ ions occupy all the eight tetrahedral voids of the unit cell. (iv) S2– ions form fcc lattice and Zn2+ ions go into alternate tetrahedral voids of the unit cell.

Answer»

(i) Cl– ion form fcc lattice and Na+ ions occupy all octahedral voids of the unit cell. 



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