1.

In Whichof the followingoptionsorder ofarrangementdoes notagree withthe variationof property indicatedagainst it ?

Answer»

`A1^(3+) lt Mg^(2+) lt Na^(+) lt F^(-)` ( increasingionicsize )
`B lt C lt N lt O ` (increasingfirst ionisation enthalpy )
`I lt Br lt C lt F` (increasingelectron gain enthalpy )
`Li lt Na lt K lt Rb` (increasingmetallicradius )

Solution :the ionicsize increasesas the + Ve CHARGEON the cation decreasesor the -vecharge on theanion increase
Thereforeoption(a) iscorrect.
than thatof O.Thusoption(b) isincorrect.
Dueto greaterstabilityof the half-filledelectronicconfigurationor OFN its IONIZATIONENTHALPYIS higher than thatof O. Thusoption ( b) isincorrect.
Duttostrongerelectron- electronrepulsion in thed smallsizeof F thenegativeelectron gainenthalpy ofF ISLOWER thanthat of C1 .Thusoption( c) isincorrect.
Themetalliccharacterincreasesas the sizeof the metallicatomincrease. thusoption (d) iscorrect.
Thusoptions ( b) and (c) AREINCORRECT.


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