1.

Inaqueous solution, the ionization constants for carbonic acid are K_(1)=4.2xx10^(-7) and K_(2)=4.8xx10^(-11). Select the correct statement for asaturated 0.034 M solution of the carbonic acid.

Answer»

The concentrations of `H^(+)` and `HCO_(3)^(-)` are APPROXIMATELY equal.
The concentration of `H^(+)` is double that of `CO_(3)^(-)`.
The concentration of `CO_(3)^(2-)` is 0.034 M.
The concentration of `CO_(3)^(2-) ` isgreater than that of `HCO_(3)^(-)`.

Solution :`H_(2)CO_(3)hArr H^(+)HCO_(3)^(-), K_(1)=4.2xx10^(-7)`
`HCO_(3)^(+)hArrH^(+)+CO_(3)^(2-),K_(2)=4.8xx10^(-11)`
As `K_(2)lt lt K`, concentrations of `H^(+)` and `HCO_(3)^(-)` will be approximately equal.


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