1.

Iodine does not react with ethane though I2 is more easily cleaved homolytically than the other halogens. Explain.

Answer»

Bond dissociation enthalfy of I2 is less as compared to that of Cl2 and Br2 which means that the homolysis of I2 is the easier. However , HI formed in a reaction is a strong reducing agent and it makes the reaction reversible. Therfore, iodine does not reacts reversible. Therfore, iodine does not reacts with ethane. 

CH3 – CH3 +I2 -------------> CH3 – CH2 – I + HI 

Ethane                                     Iodoethane



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