1.

Iodine titration can be iodemotric or iodimetric depending on using iodine directly or indirectly is an oxidising agent in the redox titration. a. Iodimetric titration in which a standard iodine solution is used as an oxidant and iodine is directly or indirectly titrated against a reducing agent. For example. 2CuSO_(4)+4KJtoCu_(2)I_(2)+2K_(2)SO_(4)+I_(2) b. Iodimetric procedures are used for the datermination of strength of reducing agent such as thiosulphates, sulphites, arsenties adn stanous chloride etc. by titrating them against standard solution of iodine in a burette. 2Na_(2)SO_(3)to2 NaI +Na_(2)S_(4)O_(6) Starch is used as indicator near the end point whilch form blue colour complex with I_(3)^(-). The blue colour disappeams whenthere is not more of free I_(2) . The volume of KI solutioin used for CuSO_(4) will be

Answer»

100 ml
40 ml
400 ml
200 ml

Solution :EQ. of `S_(2)O_(3)^(-2)` = Eq. of `I^(-)`
`1XX(100)/(1000)xx1=0.5xx1xxV`
`V=0.2` lit implies `V=200ml`


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