1.

Is there an expansion or a contraction as titanium transforms from hep to body-centered Cubic ?The atomic radius of titanium is 145.8 pm in hep but 142.5 pm is bcc.

Answer»

Expansion of `3.2 %`
Expansion of `1.016`
CONTRACTION of `3.2 %`
Contraction of `1.016`

SOLUTION :The volume CHANGE is a result of two partically contracting factors: (1) different
packing fraction (f), and (2) different RADII
`(V("bcc"))/(V("hcp"))=(f("hcp"))/(f("bcc"))xx(V("bcc"))/(V("hcp"))`
f(hcp)=0.7404,f(bcc)=0.6802
`(V_("bcc"))/(V("hcp"))/(V_("hcp"))=(0.7404)/(0.6802)xx((142.5)^(3))/((145.8)^(3))=1.016`


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