1.

It is becauseof inability of ns^(2)electrons of the valence shell to participate inbonding that

Answer»

`Sn^(2+)` is oxidising while`Pb^(4+)` is REDUCING
`Sn^(2+)` and `Pb^(2+)` are both oxidising and reducing
`Sn^(4+)`is reducingwhile `Pb^(4+)` is oxidising
`Sn^(2+)` is reducing while `Pb^(4+)` oxidising

Solution :Since inert pair effect becomesmore PRONOUNCED down the GROUP,therefore +4 oxidationstable of Sn is more stable than its +2 oxidatationstate andhence `Sn^(2+)` loses two electronsand thus acts a reducing agent.
`underset(" Less stable ")(Sn^(2+))rarr underset(" More stable ")(Sn^(4+)) + 2e^(-)`
In contrast, +2 oxidationstate of Pb is more STABLETHAN its +4 oxidationstate,therefore `Pb^(4+)`acceptstwo electrons andthus actsas an oxidising agent.
`underset(" Less stable ")(Pb^(4+)) + 2e^(-) rarr underset(" More stable ")(Pb^(2+))`
Thus, option (d) is CORRECT.


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