1.

K_(1) & K_(2) for oxalic acid are 6.5 xx 10^(-2) and 6.1 xx 10^(-5) respectively . What will be the [OH^(-)] in a 0.01 M solution of sodium oxalate

Answer»

`9.6 xx 10^(-6)`
`1.4 xx 10^(-1)`
`1.2 xx 10^(-6)`
`1.3 xx 10^(-8)`

Solution :The hydrolysis of `C_(2)O_(4^(2-))` is as follows
`C_(2)O_(4^(2-)) + H_(2)O hArr HC_(2)O_(4)^(-) + OH^(-)`
`[OH^(-)] = sqrt((K_(W) xx C)/(K_(2))) = sqrt((10^(-14) xx 10^(-2))/(6.1 xx 10^(-5)))`
`= 1.2 xx 10^(-6)`


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