1.

KFhas ccp structure. Calculate the radius of unit cell if the side of the cube or edge length is 400 pm.How manyFe^(-)ions and octahedral voids are there in the unitcell ?

Answer»

Solution :ccpis same as fcc, hence,`r= a/ (2sqrt2) = 0.3535 a = 0.3535 xx 400 "pm" = 141.4 ` pm.
In fcc, struture, THER are ` 4 F^(-)`ions in the PACKING and hence 4 octahedral VOIDS.


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