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Knowing the electron gain enthalpy values for `O rarr O^(Ө)` and `O rarr O^(2-)` as `- 141 kJ mol^-1` and `+ 702 kJ mol^-1` respectively, how can you account for the formation of a large number of oxides having `O^(2-)` species and not `O^(Ө)` ? |
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Answer» Formation of `MO_2` and `MO` involves the following steps: `M_(g)overset(triangle_iH_l)toM^(o+)overset(triangle_iH_2)toM^(2+)` `Ooverset(triangle_(eg)H_l)toO^(ɵ)underset("Energy")overset("Lattice")toM^(2+)(O^(ɵ))_(2(s))`. `M^(2+)+O^(2-)underset("energy")overset("lattice")toM^(2+)O^(2-)` (i). `O^(2-)` has a stable noble gas configuration. (ii). Due to higher charge on `O^(2-)` than on `O^(ɵ)` ions, tha lattice energy released during the formation of oxides containing `O^(2-)` ion is much larger than during the formation of oxides containing `O^(ɵ)` ion. Hence formation of oxides containing `O^(2-)` species is energetically more favourable than oxides containing `O^(ɵ)` species. |
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