

InterviewSolution
Saved Bookmarks
1. |
Liquid `NH_(3)` ionises to a slight extent. At `-50^(@)C`, its ionic product `K_(NH_(3)) = [overset(Θ)Nh_(4)] [overset(Θ)NH_(2)]` is `10^(-30)`. How many amide ions, `overset(o+)NH_(2)` are present per `mm^(3)` of pure liquid `NH_(3)`? |
Answer» `2NH_(3) hArr overset(oplus)(N)H_(4)+ overset(oplus)(N)H_(2)` `K_(NH_(3)) = [overset(o+)NH_(4)] [overset(Θ)NH_(2)] = 10^(-30)` Since each ion ins produced in equal number of moles `:. [overset(Θ)NH_(2)] = [overset(o+)NH_(4)] = 10^(-15)M` Number of `"ions/ mm"^(3)` `= ((10^(-15) "mol")/(L)) ((1L)/(10^(6)mm^(3))) ((6xx10^(23) ions)/("mol"))` `= (10^(-15)xx1xx6 xx 10^(23))/(10^(6)) = 600 "ions mm"^(-3)` |
|