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Liquid water freezes at 273K under external pressure of 1atm . The process is at eruilibrium H_(2)O(l)toH_(2)O(S)at 273 Kand 1atm however , it required to calculate the thermodynamic parameters of the fusion process occurring at same pressure and different temperature . Using the following dat ,answer the questions thaat follow: d_(ice)=0.9gm //cc,d_(H_(2)O(l))=1gm //c"c",1L-atm =101.3 J C_(p)[H_(2)O(s)]=36.4JK^(-1)mol^(-1) C_(p)[H_(2)O(l)]=75.3Jk^(-1)mol^(-1) DeltaH_("fusion")=6008.2mol^(-1).Alldataat 273K. At 1 atm and at different temperature given below Match the conditions and the temperature for the ' fusion ' process. {:(Condition,Temperature ),((a)Spontaneous ,(P)273K ),((B)At equilibrium ,(Q)260K ),((c)"Not feasible",(R)280k):} |
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Answer» (A-R),(B-P),(C-Q) |
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