1.

Markovnikov addition takes place with unsymmetrical alkenes. The positive part of the reagent gets connected to the double bonded carbon with more number of hydrogens. In presence of peroxide and in special cases addition takes place against Markovnikov rule. In which of the following compound addition takes place against Markovnikov rule

Answer»

`CF_2 = CF_2`
`C Cl_3 - CH = CH_2`
`CH_3-underset(Cl)underset(|)C=CH_2`

Solution : `C Cl_3` is a strong with DRAWING group. So `pi` BOND polarise in its direction and ADDITION takes palce against Markovniko rule


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